|1,2,4-TRICHLOROBENZENE||ICSC: 1049 (November 2003)|
| CAS #: 120-82-1
| UN #: 2321
|EC Number: 204-428-0
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Gives off irritating or toxic fumes (or gases) in a fire.||NO open flames.||Use water spray, powder, foam, carbon dioxide.|
|PREVENT GENERATION OF MISTS!|
|Inhalation||Cough. Sore throat. Burning sensation.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||Dry skin. Redness. Roughness.||Protective gloves.||Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .|
|Eyes||Redness. Pain.||Wear safety goggles or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal pain. Sore throat. Vomiting.||Do not eat, drink, or smoke during work.||Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. If solid: sweep spilled substance into sealable containers. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Separated from strong oxidants, acids and food and feedstuffs.|
|Do not transport with food and feedstuffs.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 5 ppm as STEL.
MAK: skin absorption (H); carcinogen category: 3.
EU-OEL: 15.1 mg/m3, 2 ppm as TWA; 37.8 mg/m3, 5 ppm as STEL; (skin)
|The substance is toxic to aquatic organisms. Bioaccumulation of this chemical may occur in fish.|
|The occupational exposure limit value should not be exceeded during any part of the working exposure.
See ICSCs 0344 and 1222.
Symbol: Xn, N; R: 22-38-50/53; S: (2)-23-37/39-60-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|