|DICROTOPHOS||ICSC: 0872 (March 1998)|
|(E)-3 (Dimethyloamino)-1-methyl-3-oxoprop-1-enyl dimethyl phosphate
Dimethyl cis-2-dimethylcarbamoyl-1-methylvinyl phosphate
| CAS #: 141-66-2
| UN #: 3018
|EC Number: 205-494-3
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 93°C explosive vapour/air mixtures may be formed. Risk of fire and explosion if formulations contain flammable/explosive solvents.||NO open flames. Above 93°C use a closed system and ventilation.||Use water spray, powder, foam, carbon dioxide.|
|PREVENT GENERATION OF MISTS! STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Nausea. Dizziness. Vomiting. Laboured breathing. Sweating. Pupillary constriction, muscle cramp, excessive salivation. Unconsciousness. Convulsions.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Muscle twitching. Further see Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Blurred vision.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal cramps. Diarrhoea. Vomiting. Further see Inhalation.||Do not eat, drink, or smoke during work. Wash hands before eating.||Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Separated from food and feedstuffs. Keep in a well-ventilated room. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.|
|Do not transport with food and feedstuffs.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
|TLV: 0.05 mg/m3, as TWA; (skin); A4 (not classifiable as a human carcinogen); BEI issued|
|The substance is toxic to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to birds. Avoid release to the environment in circumstances different to normal use.|
|The substance is stable when stored in glass or polyethylene containers up to 40°C.
Explosive limits are unknown in literature, although the substance is combustible.
Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.
Symbol: T+, N; R: 24-28-50/53; S: (1/2)-28-36/37-45-60-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|