|ENDOSULFAN (MIXED ISOMERS)||ICSC: 0742 (March 1998)|
6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide
| CAS #: 115-29-7
| UN #: 2761
|EC Number: 204-079-4
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Not combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.||In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water.|
|PREVENT DISPERSION OF DUST! STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||See Ingestion.||Use local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||MAY BE ABSORBED! See Ingestion.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Blue lips, fingernails and skin. Confusion. Headache. Weakness. Dizziness. Nausea. Vomiting. Diarrhoea. Convulsions. Laboured breathing. Unconsciousness.||Do not eat, drink, or smoke during work. Wash hands before eating.||Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Rest. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT wash away into sewer. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Provision to contain effluent from fire extinguishing. Separated from acids, bases, iron and food and feedstuffs. Dry. Well closed.|
|Do not transport with food and feedstuffs.
Severe marine pollutant.
|ENDOSULFAN (MIXED ISOMERS)||ICSC: 0742|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
|TLV: 0.1 mg/m3, as TWA; (skin); A4 (not classifiable as a human carcinogen)|
|The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to birds and soil organisms. Bioaccumulation of this chemical may occur in aquatic organisms. The substance may cause long-term effects in the aquatic environment. Avoid release to the environment in circumstances different to normal use.|
|Use of alcoholic beverages enhances the harmful effect.
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.
Symbol: T, N; R: 24/25-36-50/53; S: (1/2)-28-36/37-45-60-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|