|2-MERCAPTOBENZOTHIAZOLE DISULFIDE||ICSC: 0505 (April 2017)|
| CAS #: 120-78-5
| UN #: 3077
|EC Number: 204-424-9
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Finely dispersed particles form explosive mixtures in air.||NO open flames. PREVENT DISPERSION OF DUST. Prevent deposition of dust. Closed system, dust explosion-proof electrical equipment and lighting.||Use water spray, dry powder, foam, carbon dioxide.|
|AVOID ALL CONTACT!|
|Inhalation||Use local exhaust or breathing protection.||Fresh air, rest.|
|Skin||Protective gloves. Protective clothing.||Wear protective gloves when administering first aid. Remove contaminated clothes. See Notes. Rinse and then wash skin with water and soap.|
|Eyes||Redness.||Wear safety goggles.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Do not eat, drink, or smoke during work.||Rinse mouth.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: face shield and particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
WARNINGMay cause an allergic skin reaction
Very toxic to aquatic life with long lasting effects
|Store only in original container. Separated from strong oxidants. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.|
|2-MERCAPTOBENZOTHIAZOLE DISULFIDE||ICSC: 0505|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
|MAK: sensitization of skin (SH)|
|The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised not to let the chemical enter into the environment because it is persistent.|
|Do NOT take working clothes home.
Isolate contaminated clothing by sealing in a bag or other container.
2-Mercaptobenzothiazole (MBT, see ICSC #1183) a substance closely related to MBTS, is classified by IARC for its carcinogenicity.
Anyone who has shown skin sensitization due to this substance should avoid all further contact.
Symbol: Xi, N; R: 31-43-50/53; S: (2)-36/37-60-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|