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ICSC 0362 - SULFURIC ACID, concentrated (> 51% and < 100%)
SULFURIC ACID, concentrated (> 51% and < 100%)
ICSC: 0362
Peer-Review Status: 26.06.2015 Validated
Oil of vitriol
CAS #: 7664-93-9 RTECS #: WS5600000
UN #: 1830
EC #: 016-020-00-8
EINECS #: 231-639-5
    Formula: H2SO4
Molecular mass: 98.1

TYPES OF HAZARD
/ EXPOSURE
ACUTE HAZARDS / SYMPTOMS PREVENTION FIRST AID / FIRE-FIGHTING
FIRE Not combustible. Many reactions may cause fire or explosion. Gives off irritating or toxic fumes (or gases) in a fire.  NO contact with incompatible substances. See Chemical Dangers.  NO water. In case of fire in the surroundings, use appropriate extinguishing media. 
EXPLOSION Risk of fire and explosion on contact with bases, combustible substances, oxidizing agents, reducing agents, water or organic materials.    In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water. 
 
EXPOSURE   PREVENT GENERATION OF MISTS! AVOID ALL CONTACT!  IN ALL CASES CONSULT A DOCTOR! 
Inhalation Burning sensation. Sore throat. Cough. Laboured breathing. Shortness of breath. Symptoms may be delayed. See Notes.  Use ventilation, local exhaust or breathing protection.  Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention. 
Skin Redness. Pain. Blisters. Serious skin burns.  Protective gloves. Protective clothing.  Wear protective gloves when administering first aid. First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer immediately for medical attention. 
Eyes Redness. Pain. Severe burns.  Wear face shield or eye protection in combination with breathing protection.  Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer immediately for medical attention. 
Ingestion Burns in mouth and throat. Burning sensation behind the breastbone. Abdominal pain. Vomiting. Shock or collapse.  Do not eat, drink, or smoke during work.  Rinse mouth. Give nothing to drink. Do NOT induce vomiting. Refer immediately for medical attention. 

SPILLAGE DISPOSAL
PACKAGING & LABELLING
Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in dry sand or inert absorbent. Do NOT absorb in saw-dust or other combustible absorbents. Cautiously neutralize remainder with lime or soda ash.  Unbreakable packaging.
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs. 
EC Classification
Symbol: C; R: 35; S: (1/2)-26-30-45; Note: B 
UN Classification
UN Hazard Class: 8; UN Pack Group: II 
GHS Classification
Signal: Danger
Fatal if inhaled
Causes severe skin burns and eye damage
May cause respiratory irritation
May be corrosive to metals
See Notes 
skull;toxiccorr

EMERGENCY RESPONSE SAFE STORAGE
NFPA Code: H3; F0; R2; W.  Dry. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Store only in original packaging. Store in an area having corrosion resistant concrete floor. 

IMPORTANT DATA
Physical State; Appearance
ODOURLESS COLOURLESS OILY HYGROSCOPIC LIQUID. 

Physical dangers
No data. 

Chemical dangers
The substance is a strong oxidant. It reacts with combustible and reducing materials. The substance is a strong acid. It reacts violently with bases and is corrosive to most common metals forming a flammable/explosive gas (hydrogen - see ICSC 0001). Reacts violently with water and organic materials. This generates heat. See Notes. Attacks many plastics. Decomposes on heating. This produces irritating or toxic fumes (or gases) and sulfur oxides. 

Occupational exposure limits
MAK (inhalable fraction): 0.1 mg/m³; Carcinogen category: 4; Peak limitation category: I(1); Pregnancy risk group: C; (DFG 2004). 

Routes of exposure
Serious local effects by all routes of exposure. The substance can be absorbed into the body by inhalation of its aerosol. 

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed. 

Effects of short-term exposure
The substance is very corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Exposure could cause asphyxiation due to swelling in the throat. Inhalation of high concentrations may cause lung oedema, but only after initial corrosive effects on the eyes and the upper respiratory tract have become manifest. Inhalation may cause asthma-like reactions (RADS). Medical observation is indicated. See Notes. 

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis. Repeated or prolonged inhalation may cause effects on the lungs. Risk of tooth erosion upon repeated or prolongated exposure to an aerosol of this substance. Mists of this strong inorganic acid are carcinogenic to humans. See Notes. 


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Decomposes at 340°C
Melting point: 10°C
Relative density (water = 1): 1.8 (20°C)
Solubility in water at 20°C: miscible
Vapour pressure, Pa at 20°C: < 10 (negligible)
Relative vapour density (air = 1): 3.4  
The substance is harmful to aquatic organisms. 

NOTES
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.
Some studies have shown a link between the inhalation of strong inorganic acid mists and cancer. Some organisations may therefore decide to classify and label for carcinogenicity under GHS.
NEVER pour water into this substance; when dissolving or diluting always add it slowly to the water.
Other UN numbers: UN1831 Sulfuric acid, fuming, hazard class 8, subsidiary hazard 6.1, pack group I; UN1832 Sulfuric acid, spent, Hazard class 8, Pack group II. 

ADDITIONAL INFORMATION
 

IPCS
International
Programme on
Chemical Safety
WHO ILO EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
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