|4-NITROANILINE||ICSC: 0308 (December 2001)|
| CAS #: 100-01-6
| UN #: 1661
|EC Number: 202-810-1
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Many reactions may cause fire or explosion. Finely dispersed particles form explosive mixtures in air.||NO open flames. NO contact with combustible substances. Closed system, dust explosion-proof electrical equipment and lighting. Prevent deposition of dust.||Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. Combat fire from a sheltered position.|
|PREVENT DISPERSION OF DUST!|
|Inhalation||Blue lips, fingernails and skin. Headache. Dizziness. Nausea. Confusion. Convulsions. Laboured breathing. Unconsciousness.||Use local exhaust or breathing protection.||Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Further see Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .|
|Eyes||Redness. Pain.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Further see Inhalation.||Do not eat, drink, or smoke during work. Wash hands before eating.||Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water.||
According to UN GHS Criteria
|Separated from strong acids, strong oxidants, combustible substances, reducing agents and food and feedstuffs. Dry.|
|Do not transport with food and feedstuffs.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 3 mg/m3, as TWA; (skin); A4 (not classifiable as a human carcinogen); BEI issued.
MAK: skin absorption (H); carcinogen category: 3
|The substance is harmful to aquatic organisms.|
|Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
See ICSCs 0306 and 0307.
Symbol: T; R: 23/24/25-33-52/53; S: (1/2)-28-36/37-45-61; Note: C
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