Phosphorothioic acid O,O-diethyl O-(6-methyl-2-(1-methylethyl)-4-pyrimidinyl) ester
| CAS #: 333-41-5|
| UN #: 3018
|EC Number: 206-373-8
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion if formulations contain flammable/explosive solvents.||NO open flames.||Use water spray, powder, foam, carbon dioxide.|
|AVOID ALL CONTACT! FIRST AID: USE PERSONAL PROTECTION.|
|Inhalation||Muscle twitching. Pupillary constriction, muscle cramp, excessive salivation. Sweating. Nausea. Dizziness. Convulsions. Unconsciousness. Laboured breathing.||Use ventilation, local exhaust or breathing protection. Avoid inhalation of mist.||Fresh air, rest. Artificial respiration may be needed. Refer immediately for medical attention. See Notes.|
|Skin||MAY BE ABSORBED! Redness. Pain. Further see Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer immediately for medical attention . See Notes.|
|Eyes||Redness. Pain.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal cramps. Diarrhoea. Further see Inhalation.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Refer immediately for medical attention. See Notes.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
DANGERToxic if swallowed
Harmful if inhaled
May cause cancer
Causes damage to nervous system
Causes damage to the nervous system through prolonged or repeated exposure
Very toxic to aquatic life with long lasting effects
|Provision to contain effluent from fire extinguishing. Separated from strong oxidants, strong acids, bases and food and feedstuffs. Keep in a well-ventilated room. Store in an area without drain or sewer access.|
|Do not transport with food and feedstuffs.
Severe marine pollutant.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C12H21N2O3PS / (CH3)2CHC4N2H(CH3)OPS(OC2H5)2
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.01 mg/m3, as TWA; (skin); A4 (not classifiable as a human carcinogen); BEI issued.
MAK: (inhalable fraction): 0.1 mg/m3; peak limitation category: II(2); skin absorption (H); pregnancy risk group: C
|The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. This substance may be hazardous to the environment. Special attention should be given to birds and bees. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.|
|Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|