| CAS #: 126-99-8|
| UN #: 1991 (inhibited)
|EC Number: 204-818-0
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Highly flammable. Many reactions may cause fire or explosion. Gives off irritating or toxic fumes (or gases) in a fire. Vapour/air mixtures are explosive.||NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Use non-sparking handtools.||Use powder, water spray, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Cough. Sore throat. Headache. Dizziness. Drowsiness. Laboured breathing. Heart palpitations. Unconsciousness.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Refer immediately for medical attention.|
|Skin||MAY BE ABSORBED! Redness. Pain. Burning sensation. See Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer immediately for medical attention.|
|Eyes||Redness. Pain. Corneal damage.||Wear safety goggles, face shield or eye protection in combination with breathing protection.||Rinse with plenty of water (remove contact lenses if easily possible). Refer for medical attention.|
|Ingestion||See Inhalation.||Do not eat, drink, or smoke during work.||Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.||
According to UN GHS Criteria
DANGERHighly flammable liquid and vapour
Toxic if swallowed
Causes skin irritation
Causes serious eye irritation
Suspected of causing cancer
Causes damage to organs
May cause damage to organs through prolonged or repeated exposure
|Fireproof. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Cool. Keep in the dark. Well closed. Store only if stabilized. Store in an area without drain or sewer access.|
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C4H5Cl / CH2=CClCH=CH2
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 1 ppm as TWA; (skin); A2 (suspected human carcinogen).
MAK: skin absorption (H); carcinogen category: 2
|An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
The odour warning when the exposure limit value is exceeded is insufficient.
Do NOT use in the vicinity of a fire or a hot surface, or during welding.
Check for peroxides prior to distillation; eliminate if found.
Inhibitors such as hydroquinone or phenothiazine are generally added when it is to be stored.
Do NOT take working clothes home.
Symbol: F, T; R: 45-11-20/22-36/37/38-48/20; S: 53-45; Note: D, E
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|