|ALLYL GLYCIDYL ETHER||ICSC: 0096 (May 2018)|
Allyl 2,3-epoxypropyl ether
| CAS #: 106-92-3
| UN #: 2219
|EC Number: 203-442-4
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Flammable. Above 48°C explosive vapour/air mixtures may be formed.||NO open flames, NO sparks and NO smoking. Above 48°C use a closed system, ventilation and explosion-proof electrical equipment.||Use powder, foam, carbon dioxide, water. In case of fire: keep drums, etc., cool by spraying with water.|
|AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Cough. Sore throat. Burning sensation. Drowsiness. Lethargy.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Artificial respiration may be needed. Refer immediately for medical attention.|
|Skin||MAY BE ABSORBED! Dry skin. Redness. Pain. Blisters.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain. Blurred vision. Severe deep burns.||Wear face shield, safety goggles or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Burning sensation. Headache. Dullness. Drowsiness. Nausea. Vomiting.||Do not eat, drink, or smoke during work.||Rinse mouth. Give one or two glasses of water to drink. Refer immediately for medical attention.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in inert absorbent. Wash away remainder with plenty of water. Store and dispose of according to local regulations. Do NOT let this chemical enter the environment.||
According to UN GHS Criteria
DANGERFlammable liquid and vapour
Harmful if swallowed
Toxic if inhaled
Causes skin irritation
May cause an allergic skin reaction
Causes serious eye damage
May cause drowsiness or dizziness
Suspected of causing genetic defects
Suspected of causing cancer
Suspected of damaging fertility or the unborn child
Harmful to aquatic life
|Fireproof. Separated from strong oxidants, strong bases and strong acids. Cool. Keep in the dark.|
|ALLYL GLYCIDYL ETHER||ICSC: 0096|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 1 ppm as TWA; A4 (not classifiable as a human carcinogen).
MAK: carcinogen category: 2; skin absorption (H); sensitization of skin (SH)
|The substance is harmful to aquatic organisms.|
|Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 61°C.
Use of alcoholic beverages enhances the harmful effect.
Depending on the degree of exposure, periodic medical examination is suggested.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.
The odour warning when the exposure limit value is exceeded is insufficient.
Check for peroxides prior to distillation; eliminate if found.
Symbol: Xn; R: 10-20/22-37/38-40-41-43-52/53-62-68; S: (2)-24/25-26-36/37/39-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|