|LEAD||ICSC: 0052 (November 2019)|
| CAS #: 7439-92-1
| UN #: 3077 (n.o.s.)
|EC Number: 231-100-4
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.||Closed system, ventilation, explosion-proof electrical equipment and lighting.||In case of fire in the surroundings, use appropriate extinguishing media.|
|PREVENT DISPERSION OF DUST! STRICT HYGIENE!|
|Inhalation||Cough. Metallic taste. Abdominal pain. Headache. Confusion. Drowsiness. Unconsciousness. Convulsions.||Use local exhaust or breathing protection.||Fresh air, rest. Refer immediately for medical attention. See Notes.|
|Skin||Protective gloves.||Remove contaminated clothes. Rinse and then wash skin with water and soap.|
|Eyes||Redness.||Wear safety spectacles.||Rinse with plenty of water (remove contact lenses if easily possible).|
|Ingestion||See Inhalation.||Do not eat, drink, or smoke during work.||Rinse mouth. Refer immediately for medical attention.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
DANGERSuspected of causing cancer
May damage fertility or the unborn child
May cause harm to breast-fed children
Causes damage to organs
Causes damage to organs through prolonged or repeated exposure
Toxic to aquatic life with long lasting effects
|Store only in original container. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Store in an area without drain or sewer access.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.05 mg/m3, as TWA; A3 (confirmed animal carcinogen with unknown relevance to humans); BEI issued.
MAK: carcinogen category: 2; germ cell mutagen group: 3A.
EU-OEL: (binding): 0.15 mg/m3 as TWA
|The substance is toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised not to let the chemical enter into the environment.|
|Specific treatment may be necessary in case of poisoning with this substance.
Depending on the degree of exposure, periodic medical examination is suggested.
Do NOT take working clothes home.
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|