TRIFLUMIZOLEICSC: 1252
(E)-4-Chloro-alpha,alpha,alpha-trifluoro-N-(1-imidazol-1-yl-2-propoxyethylidene)-o-toluidine
1-[(1E)-1-[[4-chloro-2-(trifluoromethyl)phenyl]imino]-2-propoxyethyl]-1H-imidazole
(1E)-N-[4-chloro-2-(trifluoromethyl)phenyl]-1-(1H-imidazol-1-yl)-2-propoxyethanimine
May 2018
CAS #: 99387-89-0
UN #: 3077
EC Number: 614-708-8

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.        In case of fire in the surroundings, use appropriate extinguishing media.   

 STRICT HYGIENE!  
  SYMPTOMS PREVENTION FIRST AID
Inhalation   Use ventilation.  Fresh air, rest. 
Skin   Protective gloves.  Remove contaminated clothes. Rinse and then wash skin with water and soap. 
Eyes Redness.  Wear safety spectacles.  Rinse with plenty of water for several minutes (remove contact lenses if easily possible). 
Ingestion   Do not eat, drink, or smoke during work.  Rinse mouth. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. 

According to UN GHS Criteria

excl mark;warncancer;health hazenviro;aqua
DANGER
Harmful if swallowed
May cause an allergic skin reaction
Suspected of damaging fertility or the unborn child
May cause damage to liver through prolonged or repeated exposure
Very toxic to aquatic life with long lasting effects 

Transportation
UN Classification
UN Hazard Class: 9; UN Pack Group: III 

STORAGE
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Store in an area without drain or sewer access. 
PACKAGING
Do not transport with food and feedstuffs. 
TRIFLUMIZOLE ICSC: 1252
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS CRYSTALS. 

Physical dangers
No data. 

Chemical dangers
Decomposes on heating and on burning. This produces toxic and corrosive fumes including nitrogen oxides, hydrogen fluoride, hydrogen chloride and carbon monoxide. Reacts with strong acids and strong bases. This generates toxic, fire and explosion hazard. 

Formula: C15H15ClF3N3O
Molecular mass: 345.8
Melting point: 63°C
Boiling point: No boiling point at normal pressure; decomposes at 150°C
Density: 1.4 g/cm³
Solubility in water, mg/l at 20°C: 10.2 (practically insoluble)
Vapour pressure at 25°C: negligible
Octanol/water partition coefficient as log Pow: 4.8 (calculated) 


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of dust and by ingestion. 

Effects of short-term exposure
The substance is mildly irritating to the eyes. 

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. 

Effects of long-term or repeated exposure
Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the liver. This may result in impaired functions. Animal tests show that this substance possibly causes toxicity to human reproduction or development. 


OCCUPATIONAL EXPOSURE LIMITS
 

ENVIRONMENT
The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. Avoid release to the environment in circumstances different to normal use. 

NOTES
CAS No. 99387-89-0 of triflumizole is for (E) isomer. CAS No. 668694-11-1 is for unstated stereochemistry.
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties. 

ADDITIONAL INFORMATION
  EC Classification
 

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