|p-PHENYLENEDIAMINE||ICSC: 0805 (September 1997)|
| CAS #: 106-50-3
| UN #: 1673
|EC Number: 203-404-7
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Finely dispersed particles form explosive mixtures in air. Risk of fire and explosion on contact with strong oxidizing agents.||NO open flames. Closed system, dust explosion-proof electrical equipment and lighting. Prevent deposition of dust.||Use water spray, powder.|
|Inhalation||Cough. Dizziness. Headache. Laboured breathing. See Ingestion.||Use local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Redness.||Protective gloves. Protective clothing.||First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer for medical attention .|
|Eyes||Redness. Pain. Swelling of the eyelids. Blurred vision. Loss of vision.||Wear safety spectacles, face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal pain. Blue lips, fingernails and skin. Convulsions. Drowsiness. Laboured breathing. Shortness of breath. Vomiting. Weakness.||Do not eat, drink, or smoke during work.||Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT absorb in saw-dust or other combustible absorbents.||
According to UN GHS Criteria
|Separated from strong oxidants, strong acids, acid anhydrides and food and feedstuffs. Keep in the dark. Well closed.|
Do not transport with food and feedstuffs.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C6H8N2 / C6H4(NH2)2
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.1 mg/m3, as TWA; A4 (not classifiable as a human carcinogen).
MAK: (inhalable fraction): 0.1 mg/m3; carcinogen category: 3; peak limitation category: II(2); pregnancy risk group: C; skin absorption (H); sensitization of skin (SH)
|The substance is very toxic to aquatic organisms.|
|Depending on the degree of exposure, periodic medical examination is suggested.
The symptoms of asthma often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation are therefore essential.
Anyone who has shown symptoms of asthma due to this substance should avoid all further contact.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
The relation between odour and the occupational exposure limit cannot be indicated.
Rinse contaminated clothing with plenty of water because of fire hazard.
Symbol: T+, N; R: 23/24/25-36-43-50/53; S: (1/2)-28-36/37-45-60-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|