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3-VINYL TOLUENEICSC: 0734 (December 2022)
m-Methyl styrene
1-Ethenyl-3-methylbenzene
m-Vinyl toluene
CAS #: 100-80-1
UN #: 2618
EC Number: 202-889-2

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Flammable.  Above 51°C explosive vapour/air mixtures may be formed.  NO open flames, NO sparks and NO smoking.  Above 51°C use a closed system, ventilation and explosion-proof electrical equipment.  Use water spray, foam, powder, carbon dioxide.  In case of fire: keep drums, etc., cool by spraying with water. 

 PREVENT GENERATION OF MISTS!  
  SYMPTOMS PREVENTION FIRST AID
Inhalation Sore throat. Cough. Dizziness. Headache. Drowsiness. Vomiting. Lethargy.  Use ventilation, local exhaust or breathing protection.  Fresh air, rest. Refer for medical attention. 
Skin Dry skin. Redness.  Protective gloves.  Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention . 
Eyes Redness. Pain.  Wear safety spectacles.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Aspiration hazard! Abdominal pain. Nausea. Vomiting.  Do not eat, drink, or smoke during work.  Rinse mouth. Do NOT induce vomiting. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Remove all ignition sources. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance, protective clothing and protective gloves. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer. 

According to UN GHS Criteria

flam;flameexcl mark;warncancer;health hazenviro;aqua
DANGER
Flammable liquid and vapour
Harmful if inhaled
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
May be fatal if swallowed and enters airways
Toxic to aquatic life with long lasting effects 

Transportation
UN Classification
UN Hazard Class: 3; UN Pack Group: III 

STORAGE
Fireproof. Separated from strong oxidants and strong acids. Well closed. Store only if stabilized. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access. 
PACKAGING
Marine pollutant. 
3-VINYL TOLUENE ICSC: 0734
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
LIGHT YELLOW LIQUID WITH CHARACTERISTIC ODOUR. 

Physical dangers
Vapours are uninhibited and may polymerize, causing blockage of vents. 

Chemical dangers
The substance may polymerize if it is not stabilized. This generates fire or explosion hazard. Reacts violently with strong oxidants and strong acids. 

Formula: CH3C6H4CH=CH2 / C9H10
Molecular mass: 118.2
Boiling point: 164°C
Melting point: -86°C
Density: 0.91 g/cm³
Solubility in water, mg/l at 25°C: 89 (practically insoluble)
Vapour pressure, kPa at 20°C: 0.23
Relative vapour density (air = 1): 4.1
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00
Flash point: 51°C c.c.
Auto-ignition temperature: 493°C
Explosive limits, vol% in air: 1.9-6.1
Octanol/water partition coefficient as log Pow: 3.580  


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion. 

Effects of short-term exposure
The substance is irritating to the eyes, skin and respiratory tract. The substance may cause effects on the nervous system. If swallowed the substance easily enters the airways and could result in aspiration pneumonitis. 

Inhalation risk
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C. 

Effects of long-term or repeated exposure
The substance defats the skin, which may cause dryness or cracking. The substance may have effects on the liver. 


OCCUPATIONAL EXPOSURE LIMITS
MAK: 98 mg/m3, 20 ppm; peak limitation category: I(2); pregnancy risk group: D.
TLV (see Notes) 

ENVIRONMENT
The substance is toxic to aquatic organisms. Bioaccumulation of this chemical may occur in the environment. It is strongly advised not to let the chemical enter into the environment. 

NOTES
See ICSC 0514. 

ADDITIONAL INFORMATION
  EC Classification
 

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