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Document ID (ISN)22745
CIS number 75-618
ISSN - Serial title 0009-2347 - Chemical and Engineering News
Year 1974
Convention or series no.
Author(s) Bruce M.I.
Title Borane-tetrahydrofuran.
Bibliographic information 14 Oct. 1974, Vol.52, No.41, p.3.
Abstract The author of this letter to the editor reports the spontaneous explosion of a glass bottle containing 900g of a 1M solution of the borane-tetrahydrofuran complex in tetrahydrofuran. The bottle was shattered into small fragments. The sample had been shipped to Australia from England at temperatures below 15°C, and the bottle was unopened and had stood undisturbed for 2 weeks. A reply follows by a manufacturer of the reagent, Aldrich-Boranes, Inc., who were aware of the problem (1 reference is quoted). The firm urges that the reagent be stored at 0°C and the bottle first opened behind a safety shield.
Descriptors (primary) tetrahydrofuran; laboratories; explosions; reagents; boranes
Descriptors (secondary) humidity; cold; chemical reactions; borane
Document type -
Subject(s) Fire and explosions
Broad subject area(s)
Browse category(ies) Inorganic substances
Explosions
Heterocyclic compounds
Boron and boranes