Document ID (ISN) | 103222 |
CIS number |
04-168 |
ISBN(s) |
0-7176-2798-5 |
Year |
2004 |
Convention or series no. |
HSE Research Report RR 189
|
Author(s) |
Satherley J., Kuzume A., Schiffrin D.J., Nichols R. Health and Safety Executive |
Title |
Rate of ammonia production in the electrolysis of silver nitrate solutions |
Bibliographic information |
HSE Books, P.O. Box 1999, Sudbury, Suffolk CO10 2WA, United Kingdom, 2004. viii, 35p. Illus. Price: GBP 10.00. Downloadable version free of charge. |
Internet access |
http://www.hse.gov.uk/research/rrpdf/rr189.pdf [in English]
|
Abstract |
The purpose of this study was to determine the amount of ammonia produced during electrolysis of silver nitrate solutions using metal and inert electrodes during the electrolytic recovery of silver. Trials using different experimental conditions and electrode systems confirmed that the nitrate was reduced to ammonia. The ammonia concentration in the solution showed that the yield of conversion of nitrate to ammonia was higher than 40%. It was found that ammonia is formed under both acid and alkaline conditions with a high yield, and that the pH fluctuates and changes very rapidly from acid to alkaline conditions at critical points in the electrolysis. |
Descriptors (primary) |
silver nitrate; electrolysis; ammonia |
Descriptors (secondary) |
report; recovery of substances; sampling and analysis; reduction |
Document type |
E - Books, reports, proceedings |
Country / State or Province | United Kingdom |
Subject(s) |
Metal production and metalworking
|
Broad subject area(s) |
Chemical safety
|
Browse category(ies) |
Inorganic substances
|